\(n_{ZnSO_4}=0.1\cdot1=0.1\left(mol\right)\)

\(ZnSO_4+2NaOH\rightarrow Zn\left(OH\right)_2+Na_2SO_4\)

\(0.1..............0.2\)

\(C_{M_{NaOH}}=\dfrac{0.2}{0.2}=1\left(M\right)\)

\(n_{NaOH}=0.25\cdot2=0.5\left(mol\right)\)

\(n_{H_2SO_4}=0.25\cdot1=0.25\left(mol\right)\)

\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)

\(0.5..............0.25................0.25\)

\(\left[Na^+\right]=\dfrac{0.25\cdot2}{0.25+0.25}=1\left(M\right)\)

\(\left[SO_4^{2-}\right]=\dfrac{0.25}{0.25+0.25}=0.5\left(M\right)\)

`n_{BaCl_2}=200.10^{-3}.1=0,2(mol)`

`n_{KCl}=100.10^{-3}.2=0,2(mol)`

`->n_{Cl^-}=2n_{BaCl_2}+n_{KCl}=0,6(mol)`

`->[Cl^-]={0,6}/{(200+100).10^{-3}}=2M`

\(n_{HCl}=Cm.V=1.0,1=1mol\)

\(n_{H_2SO_4}=Cm.V=0,5.0,1=0,05mol\)

Thể thích của dd D là 200ml = 0,2l

\([H^+]=\frac{n_{HCl}+2.n_{H_2SO_4}}{V}=\frac{0,1+0,1}{0,2}=1M\)

\([Cl^-]=\frac{n_{HCl}}{V}=\frac{0,1}{0,2}=0,5M\)

\([SO_4^{2-}]=\frac{n_{H_2SO_4}}{V}=\frac{0,05}{0,2}=0,25M\)

Khi cho dd D vào \(Ba\left(OH\right)_2\) chỉ có \(H_2SO_4\) tác dụng, tạo kết tủa

\(H_2SO_4+Ba\left(OH\right)_2\rightarrow BaSO_4+2H_2O\)

\(0,05....\rightarrow0,05mol\)

\(\rightarrow m_{BaSO_4}=n.M=0,05.233=11,65g\)

\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(V=0.1+0.1=0.2\left(l\right)\)

\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)

\(b.\)

\(pH=14+log\left[OH^-\right]=14+log\left(0.1\right)=13\)

\(c.\)

\(H^++OH^-\rightarrow H_2O\)

\(0.02........0.02\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.02}{1}=0.02\left(l\right)\)

\(a.\)

\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(V=0.1+0.1=0.2\left(l\right)\)

\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[OH^+\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)

\(b.\)

\(pH=14+log\left(0.1\right)=13\)

\(c.\)

\(H^++OH^-\rightarrow H_2O\)

\(0.02.......0.02\)

\(V_{H_2SO_4}=\dfrac{0.02}{1}=0.02\left(l\right)\)

a) Ta có: \(n_{NaOH}=0,1\cdot0,1=n_{KOH}=0,01\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{OH^-}=0,02\left(mol\right)\\n_{Na^+}=n_{K^+}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\left[OH^-\right]=\dfrac{0,02}{0,2}=0,1\left(M\right)\\\left[Na^+\right]=\left[K^+\right]=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)

b) Ta có: \(pH=14+log\left[OH^-\right]=13\)

c) PT ion: \(OH^-+H^+\rightarrow H_2O\)

Theo PT ion: \(n_{H^+}=n_{OH^-}=0,02\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4}=0,01\left(mol\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,01}{1}=0,01\left(l\right)=10\left(ml\right)\)

\(n_{NaOH}=0,2\left(mol\right);n_{H_2SO_4}=0,2\left(mol\right)\)

\(\Rightarrow n_{OH^-}=0,2\left(mol\right);n_{H^+}=0,4\left(mol\right)\)

 \(H^++OH^-\rightarrow H_2O\)

0,4......0,2

Lập tỉ lệ : \(\dfrac{0,4}{1}>\dfrac{0,2}{2}\)

=> H⁺ dư sau phản ứng

Dung dịch X gồm các ion:

Na⁺ : 0,2(mol)

SO4^2- : 0,2 (mol)

H⁺ dư : 0,2mol

=> \(\left[Na^+\right]=\dfrac{0,2}{0,4}=0,5M\)

\(\left[SO_4^{2-}\right]=\dfrac{0,2}{0,4}=0,5M\)

\(\left[H^+\right]=\dfrac{0,2}{0,4}=0,5M\)

$n_{NaOH} = 0,2(mol) ; n_{H_2SO_4} = 0,2(mol)$

$2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
$n_{NaOH} : 2 < n_{H_2SO_4} : 1$ nên $H_2SO_4$ dư

$n_{Na_2SO_4} = n_{H_2SO_4\ pư} = \dfrac{1}{2}n_{NaOH} = 0,1(mol)$
$V_{dd} = 0,2 + 0,2 = 0,4(lít)$
$C_{M_{Na_2SO_4}} = \dfrac{0,1}{0,4} = 0,25M$

$C_{M_{H_2SO_4\ dư}} = \dfrac{0,2-0,1}{0,4} = 0,25M$

Suy ra : 

$[Na^+] = 0,25.2 = 0,5M$

$[H^+] = 0,25.2 = 0,5M$
$[SO_4^{2-}] = 0,25 + 0,25 = 0,5M$

Đáp án B

n A l ( O H ) 3 = 0 , 1 ⇒ n A l ( O H ) 4 - = 0 , 02 n N a O H = 0 , 1 . 3 + 0 , 02 . 4 = 0 , 38 [ N a O H ] = 1 , 9